Product ID:A COMPONENTS FOR C & R FOAM 2
MSDS Date:07/22/1993
FSC:5640
NIIN:00N046154
MSDS Number: BTXPR

CLOTHIER & ROSE INC

1000 E DEL AMO BLVD
CARSON, CA 90746
US

Emergency Phone: 213-537-2800

Info Phone: 213-537-2800

Cage: 0SGD3

CLOTHIER & ROSE INC

CARSON, CA 90746 US

Telephone: 213-537-2800

Cage: 0SGD3

POLYMETHYLENE POLYPHENYL ISOCYANATE; (HIGHER OLIGOMERS OF

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: <50%

OSHA PEL N/K

ACGIH TLV: N/K

METHANE, DICHLORODIFLUORO-; (DICHLORODIFLUOROMETHANE)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: <20%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

POLYETHYLENE SHEET AND FURTHER DECONTAMINATE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

CANS. WEAR RECOM PROT GEAR. CAREFULLY VENT

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

INVERT EACH CAN SEPARATELY &

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

VALVE INTO PLASTIC LINED WASTE CNTNR. IMMED MIX

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DISP OF PROD AS YOU WOULD OTHER PLASTIC WASTE I/A/W

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

PLASTIC ACTUATOR CAP ON EACH CAN VALVE. REMOVE EXTRA

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DIRECTLY INTO PLASTIC LINED WASTE CNTNR.IMMED MIX

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

DISPOSE OF PRODUCT AS YOU WOULD OTHER PLASTIC WASTE

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

VICINITY DURING FOAMING OPER. WHEN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

ISOCYANIC ACID, METHYLENE DI-P-PHENYLENE ESTER; (4,4'

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: <50%

OSHA PEL 0.02 PPM, C

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

8.5. FLASH

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: CAN LEAD TO IRRIT OF MUC MEMBS,
TIGHTNESS OF CHEST RESP TRACT, COUGHING, HDCH, SHORTNESS OF BRTH.
MAY LEAD TO AN ALLERGIC SENSIT IN SOME PEOPLE W/ASTHMA LIKE SYMPS.
EXTENSIVE EXPOS TO CONCS WEL L ABOVE TLV COULD LEAD TO BRONCH,
BRONCH SPASM & PULM EDEMA. THESE EFTS ARE USUALLY REVERSIBLE. HIGH
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: R-12 CONCS >1000 PPM TLV MAY CAUSE
ASPHYX DUE TO OXYGEN DEPRIVATION. PEOPLE W/CARD ARRHYTHMIA MAY BE
AT INCR RISK IN SEV EXPOS. SKIN: MIX CAUSES LOCALIZED IRRIT &
DISCOLORATION. PRLNGD CONT COULD PRDCE REDDENING, SWELLING OR
BLISTERING & IN SOME INDIV, SENSIT & DERM. EYES: LIQ, VAPS/AEROSOL
IS IRRIT (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: MOVE TO AN AREA FREE OF EXPOS. GIVE OXYGEN/ARTF RESP
AS NEEDED. OBTAIN MED ATTN. EYE: FLUSH W/WATER FOR AT LST 15 MINS,
OCCAS LIFTING EYE LIDS. OBTAIN MED ATTN. SKIN: REMOVE CONTAMD
CLTHG. WASH AFFECTED AREAS THORO W/SOAP & WATER. WASH CLTHG BEFORE
REUSE. INGEST: DO NOT INDUCE VOMIT. GIVE 1-2 GLASSES OF WATER/MILK
TO DRINK. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. CONSULT
PHYS.

Flash Point:390F,199C
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HIGH EXPANSION
CHEMICAL FOAM, LARGE QUANTITY WATER SPRAY FOR LARGE FIRES.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.DURING FIRE, MDI VAPS, FLUOROCARBON VAPS, & OTHER DECOMP
PRODS THAT ARE HIGHLY TOX CAN BE GEN. SINCE(SUPDAT)
Unusual Fire/Explosion Hazard:SINCE CHEMICAL IS PACKAGED IN PRESSURIZED
AEROSOL CANS, EXPLOSIVE RUPTURE IS POSSIBLE.

Spill Release Procedures:PROVIDE VENT.SPILL SHOULD BE ABSORB W/
VERMICULITE, SAWDUST, FULLER'S EARTH/OTHER SUITABLE MEANS. POUR LIQ
DECONTAM (90% WATER, 8% CONC AMMONIUM HYDROXIDE, 2% DETERGENT) ON
SPILLAGE; ALLOW TO REACT AT LST 10 MINS. COLLECT IN OPEN
CONTAINEROR (ING 5)
Neutralizing Agent:90% WATER, 8% CONCENTRATED AMMONIUM HYDROXIDE, 2%
DETERGENT.

Handling and Storage Precautions:EDUCATE & TRAIN EMPLOYEES IN SAFE USE
OF PROD.READ ALL PACKAGE DIRECTIONS. PROT CANS FROM PHYS ABUSE. FOR
LONGEST SHELF LIFE, AVOID STORAGE ABOVE 90F.
Other Precautions:SHORT TERM STORAGE BETWEEN 40F & 60F WILL NOT HARM
MATLS. IDEAL STORAGE IS 60F-90F. STORAGE AT <40F MAY CAUSE LIQS IN
CYL TO SEPARATE THEREBY PRDCG LOWER QUALITY FOAM. AVOID SMOKING,
OPEN FLAMES/USE O F ELEC EQUIP WHICH MAY ARC IN (ING 13)

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:USE WITH ADEQUATE VENTILATION.
Protective Gloves:CHEM RESISTANT RUBBER OR PLASTIC GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKER GOGGLES
Other Protective Equipment:LONG SLEEVE WORK CLOTHES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
APPEAR/ODOR:FLUOROCARBON ODOR.FIRE FIGHT PROC:CHEM IS PACKAGED IN PRESS
AEROSOL CANS,EXPLO RUPTURE IS POSS. THEREFORE,USE COLD WATER TO
COOL FIRE EXPOS CNTNRS.EFTS OF OVEREXP:TO EYES. CORNEAL DMG CAN
OCCUR;HOWEVER, INDICATIONS ARE THAT DMGIS REVERSIBLE. INGEST:CAN
RSLT IN IRRIT & CORR ACTION IN MOUTH & DIGESTIVE TRACT

Boiling Pt:B.P. Text:SEE INGS
Vapor Pres:2700 MMHG
Vapor Density:SEE ING 1
Spec Gravity:1.3 (H2O=1)
Solubility in Water:REACTS SLOWLY
Appearance and Odor:LIQ & GASES UNDER PRESS-FROTHY LIQ UPON RELS FROM
CYL.DARK BROWN, MILD (SUPDAT)
Percent Volatiles by Volume:<20

Stability Indicator/Materials to Avoid:YES
ALCOHOLS, WATER, STRONG BASES AND METAL COMPOUNDS ARE INCOMPATIBLE WITH
"A" COMPONENT.
Stability Condition to Avoid:WATER CONTAM, OPEN FLAMES, STORAGE TEMP
>120F (49C) OR BELOW 32F (0C) SHOULD BE AVOIDED. DO NOT INCINERATE
AEROSOL CANS.
Hazardous Decomposition Products:BY HIGH HEAT OR FIRE: CARBON MONOXIDE,
OXIDES OF NITROGEN, TRACES OF HCN, MDI.
Conditions to Avoid Polymerization:CONTACT WITH MOISTURE OR OTHER
MATERIALS THAT REACT WITH ISOCYANATE. MAY OCCUR AT TEMPERATURES
OVER 400F (204C).

Waste Disposal Methods:IT IS RECOM THAT ENTIRE #12 KIT OR TOPGUN
AEROSOL REFILL BE COMPLETELY USED UP W/IN 24 HRS OF FIRST APPLIC,
HOWEVER, IF THIS HAS NOT BEEN DONE/THERE IS EXCESS "A"/"B"
COMPONENT TO DISPERSE OF, THEN US E FOLLOWING PROC. DO NOT
PUNCTURE/INCIN(ING 6)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.